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Using an inexpensive, commercially available nickel on silica alumina catalyst, in a continuous flow, packed bed reactor, three different concentration feedstocks, as well as, various conditions were investigated to determine selectivity and reaction kinetics.Selectivity to 1,2-Propanediol at all reaction conditions and feedstocks was 28-71%, while being produced at 7-19% yield.
The activation energy for glycerol was determined to be 65.9 ± 4.3 k J/mol, while for 1,2PD it was determined to be 53.7 ± 2.4 k J/mol.
At T=235°C the reaction rate for glycerol, using the 0.05M feedstock, is 6.81 μmol/g-min, 0.1M feedstock: 4.32 μmol/g-min and 0.2M feedstock: 17.21 μmol/g-min.
For 2017, the Renewable Fuel Standard imposed by the EPA calls for 19.3 billion gallons of renewable biofuels be blended into gasoline and diesel fuels, derived from petroleum.
These mandates increase the demand for biodiesel production, however they do not lead to an increased demand for the coproducts of biodiesel production, which become disposable chemicals.
phd thesis on algae production for bioenergy Maybe there is a lot of students who loves spending endless hrs focusing on academic papers?
In his spare time, you may find Dr Galadari spending time with his family; his wife, 2 sons and 2 daughters, or in a cafe reading a book. The technologies in cultivation are targeted at providing excellent growing conditions, which included modern irrigation projects, pesticidesand synthetic nitrogen fertilizer.
Awareness of the world’s finite resources and our responsibility to conserve them has led to greater emphasis on renewable energy production.
New federal mandates call for annually increasing the quantity of renewable fuels being blended with traditional petrochemical transportation fuels.
Therefore, there is incentive to convert them to more valuable products.
This research is focused on the catalytic conversion of glycerol, the major coproduct of biodiesel production, into propane diols which are more valuable.